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Editorial
- Jasper Griffioen, Ton Wildenborg
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- Journal:
- Netherlands Journal of Geosciences / Volume 95 / Issue 3 / September 2016
- Published online by Cambridge University Press:
- 13 September 2016, p. 215
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This special issue of the Netherlands Journal of Geosciences is dedicated to geoscientific research related to geological disposal of nuclear waste. Geological disposal of nuclear waste is generally accepted as the optimum solution to the problem, though it has always been politically a hot potato. It was the Secretary of Energy in the first Obama Administration who halted the Yucca Mountain national programme on nuclear waste disposal within six weeks of his appointment, without citing technical or safety issues or presenting alternatives (Alley & Alley, 2013). This contrasts sharply with the Finnish situation where the government granted a construction licence for a final disposal facility on 12 November 2015. Sweden is expected to follow soon.
First assessment of the pore water composition of Rupel Clay in the Netherlands and the characterisation of its reactive solids
- Thilo Behrends, Iris van der Veen, Alwina Hoving, Jasper Griffioen
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- Journal:
- Netherlands Journal of Geosciences / Volume 95 / Issue 3 / September 2016
- Published online by Cambridge University Press:
- 15 July 2016, pp. 315-335
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The Rupel Clay member in the Netherlands largely corresponds to the Boom Formation in Belgium, and this marine, clay-rich deposit is a potential candidate to host radioactive waste disposal facilities. Prediction of the speciation of radionuclides in Rupel Clay pore water and their retardation by interactions with Rupel Clay components requires knowledge about the composition of Rupel Clay pore water, the inventory of reactive solids and understanding of interactions between Rupel Clay and pore water. Here, we studied Rupel Clay material which was obtained from cores collected in the province of Zeeland, the Netherlands, and from drilling cuttings retrieved from a drilling in the province of Limburg, the Netherlands. Pore water was obtained by mechanical squeezing of Rupel Clay material from Zeeland. Additionally, anaerobic dilution experiments were performed in which the clay material was suspended with demineralised water or a 0.1M NaHCO3 solution. Solid-phase characterisation included determination of carbon, nitrogen and sulphur contents, measurement of cation exchange capacity (CEC) and sequential extraction of iron phases.
In contrast to the pore water in Belgian Boom Clay, pore water collected from the location in Zeeland has a higher salinity, with chloride concentrations corresponding to 70–96% of those in seawater. The high chloride concentrations most likely result from the intrusion of ions from saline waters above the Rupel Clay in Zeeland. Cation exchange during salinisation might account for the observed deficit of marine cations (Na, K, Mg) and excess of Ca concentrations, in comparison with seawater. The measured CEC values at both locations in the Netherlands vary between 7 and 35 meq(100g)−1 and are, for most samples, in the range reported for Boom Clay in Belgium (7–30meq(100g)−1).
Pore water and solid-phase composition indicate that Rupel Clay from Zeeland has been affected by oxidation of pyrite or other Fe(II)-containing solids. When coupled to the dissolution of calcium carbonates, oxidation of pyrite can account for the elevated sulphate and calcium concentrations measured in some of the pore waters. The relatively low concentrations of pyrite, organic carbon and calcite in the Rupel Clay in Zeeland, in comparison to Limburg, might be an indicator for an oxidation event. Higher contents of dithionite-extractable Fe in Rupel Clay in Zeeland (0.7–2.6mg Fe / g clay) than in Limburg (0.4–0.5mg Fe / g clay) might also be a consequence of the oxidation of Fe(II) minerals. Oxidation in the past could have accompanied partial erosion of Rupel Clay in Zeeland before deposition of the Breda Formation. However, indications are given that oxidation occurred in some of the pore waters after sampling and that partial oxidation of the cores during storage cannot be excluded. Results from dilution experiments substantiate the influence of equilibration with calcium carbonates on pore water composition. Furthermore, removal of dissolved sulphate upon interaction with Rupel Clay has been observed in some dilution experiments, possibly involving microbial sulphate reduction.
The composition of groundwater in Palaeogene and older formations in the Netherlands. A synthesis
- Jasper Griffioen, Hanneke Verweij, Roelof Stuurman
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- Journal:
- Netherlands Journal of Geosciences / Volume 95 / Issue 3 / September 2016
- Published online by Cambridge University Press:
- 27 June 2016, pp. 349-372
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There is increasing interest in the exploitation of the deep subsurface of the Netherlands for purposes other than conventional oil and gas production, such as geothermal energy, shale gas exploitation and the disposal of radioactive waste, so for technical and environmental reasons it is important to understand the composition of the deep groundwater. A synthesis has been made of almost 200 existing groundwater analyses for the Oligocene and older formations in the Netherlands. Three groundwater categories are considered: (1) deep oil and gas reservoirs, (2) deep, buried and confined aquifers and (3) shallower, semi-confined aquifers with or without outcrop areas nearby. No distinct water types are found but a continuous series, with Cl ranging from around 10,000 to 200,000 mg l−1: the highest concentrations are found in the reservoirs and the lowest in the semi-confined aquifers. The most saline brines are found in the northern onshore area and adjacent offshore area, where Permian and Triassic rock salt also occurs regionally in the subsurface. The groundwater is usually pH-neutral, saturated in carbonates and anaerobic. Anhydrite saturation occurs when the Cl concentration exceeds 100,000 mg l−1, and halite saturation occurs at Cl concentrations close to 200,000 mg l−1. Few tracer analyses have been done for δ2H–H2O, δ18O–H2O, δ37Cl, Br, Li and B, which makes a rigorous palaeohydrological interpretation impossible. Lithium and B may be controlled by water–rock interaction which makes them less suitable as tracers. Some of the analyses suggest that dissolution of rock salt plays a role in determining the salinity of groundwater for some deep wells in the southern part of the Netherlands, whereas other analyses suggest that evaporated seawater influences the salinity in the associated wells. Cation-exchange patterns and alkalinity to Ca ratios indicate that groundwater in the deep, buried and shallow, semi-confined aquifers is usually freshening. Six 14C analyses of samples from the buried aquifers indicate an apparent age of at least 20,000 years. Six δ37Cl analyses of formation waters from reservoirs in South-Holland suggest diffusion of Cl from a brine towards fresher water, and the associated K and also Li concentrations further suggest that these brines are related to rock salt dissolution and are not the residue of evaporated seawater. The high Ca concentrations are enigmatic for the hypersaline formation waters in the reservoirs. A limited series of samples had been analysed for various trace elements. The median concentrations are similar to the seawater and Dutch background concentration limits for shallow groundwater, but maximum concentrations can be up to three orders of magnitude higher. In conclusion, the data synthesis shows that the composition of groundwater in reservoirs and aquifers of Palaeogene and older age varies strongly in salinity at the national scale. Presence of evaporite deposits and diffusive transport seem to play important roles in controlling the salinity. Many existing analyses have no or only a few tracer analyses, that even vary among the samples. A complete suite of analyses is needed to elucidate the hydrogeological and geochemical processes that control the groundwater composition.